I have no interest in using OneDrive, and frankly thought I had deleted it. Its like a bad penny, it keeps coming back.
This whole mess is a result of whatever you did when you attempted to delete onedrive at some point. You didn't deal with your folders first. Onedrive would have been reinstalled with Ofc365 or an Ofc365 update. Ofc365 depends on onedrive
When I tried to shut off One Drive by going to that tutorial. My screen does not have an option to turn off or on
Again, as a result of whatever you did.
From your screenshots
Folder C:\Users\there\pictures has no location tab. (14 folders 377 files)
Folder C:\users\there\
Onedrive/Pictures\
does have a location tab. (5 files/2 folders)
Use the tutorial to move the folder location of C:\users\there\
Onedrive/Pictures to your drive F:\Pictures (verify that all files moved)
Then MANUALLY move the pictures
files from C\users\there\Pictures to F:\Pictures
Then DELETE the Pictures
folder located in C:\Users\there\
Once you know for sure that all your files are on F: disable onedrive. Do not uninstall it as the next Ofc365 update will only reinstall it. To do this,
Open Task Manager>Startup Apps
Find Onedrive.exe in the list and, right click on it, select disable. This prevents Onedrive from auto-starting.
Hopefully, this will straighten it out. If it doesn't it will require creating a new user account. Report back results.